There doesn't really seem to be anyplace to do box breaks for non-sports cards, so I'll just kind of make things up as I go along.

Broke 1 box of each of Flash Season 1, Gotham Season 1 and Supernatural Season 4-6.

Flash:

William Sadler as Simon Autograph

M18 Grant Gustin as Barry Allen Plaid Shirt Relic

DM5 Tom Cavanagh as Dr. Harrison Wells dual sweater relic

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Gotham:

Sean Pertwee as Alfred Pennyworth Autograph

M07 Zabryna Guevara as Sarah Essen Denim Relic with stitching

DM6 Andrew Stewart-Jones as Crispus Allen (blue shirt relic) & Victoria Cartagena as Renee Montoya (grey shirt relic)

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Supernatural:

Kurt Fuller as Zachariah Autograph

Mitch Pileggi as Samuel Campbell Autograph

M04 Genevieve Cortese Padalecki as Ruby II Black Relic